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This book presents the basics and characterization of defects at oxide surfaces. It provides a state-of-the-art review of the field, containing information to the various types of surface defects, describes analytical methods to study defects, their chemical activity and the catalytic reactivity of oxides. Numerical simulations of defective structures complete the picture developed. The book gives guidance to tailor oxide surfaces by controlling the nature and concentration of defects. Defects play a dominant role in the physics and chemistry of metal oxide surfaces. The central importance of surface defects to the physical chemistry of oxides is presented in this book together with the prominent role of oxides in common life. The book contains contributions from leaders in the field. It serves as a reference for experts and beginners in the field.§